Silicone surfactants have the intriguing and commercially viable ability to reduce the surface tension of polar and non-polar liquids to values 15–20 mN/m lower than commonly achieved with organic-based surfactants.
The latest developments on understanding and commercially exploiting the phenomenon of superwetting are reviewed.
Silicone surfactants demonstrate a marked tendency to form aggregate structures featuring surfactant bilayers including vesicles and lamellar liquid crystals.